expansive cement composition

In each Trial, the magnesium oxide was sieved to be within the size range indicated. A method as defined in claim 15, wherein the acid neutralization time of 1 g of the magnesium oxide in 60 ml. This magnesium oxide had an ANT of 26.4 minutes and a BET surface area of 0.82 m2 /g. Reference mortar was modified by expa nsive additive at a dosage 10% of weight of cement. The … 1980, Paris, Vol. Furthermore, expansion results from a direct chemical reaction between the tricalcium aluminate present in the Portland cement, and the calcium sulfate. added 1 N. acetic acid, is between about 15 to about 30 minutes. It is also suggested that for hotter wells with temperatures of up to 180° C., magnesium oxide calcined at 1200° to 1300° C. can serve as an expanding additive. An expandable cement composition as defined in claim 7 wherein the acid neutralization time of 1 g of the magnesium oxide in 60 ml. 2. ASSIGNMENT OF ASSIGNORS INTEREST. It will also be observed from Table 3 that increasing the weight percent of any given particle size of magnesium oxide present, invariably increases the expansion. 8 (Aug. 1, 1951); "Relations Among Particle Size, Shape, and Surface Area of Mg(OH)2 and Its Calcination Product", by V. A. Phillips et al., Journal of the American Ceramic Society, V. 61 No. A method as defined in claim 12 wherein at least about 80% of the magnesium oxide particles are between about 200 to about 300 microns in diameter. This type of cement can be manufactured by mixing clinker of natural pozzolana with OPC cement. Furthermore, for practical reasons, it will often be desirable that the expansion in the set cement must be at a practical rate under the temperature and other conditions to which it is to be exposed in use. This invention relates to an expandable cement composition. It has been discovered that this may be accomplished by providing an expansive agent in the cement, which agent will produce most of its expansion only upon the later raising of the BHST. Thus, it is apparent that increasing the calcining temperature of the magnesium oxide from 1000° C. to 1200° C., substantially increases the amount of expansion which can be produced in set cement exposed to temperatures of about 70° C. to 150° C. for periods of 14 days or more, or even periods as short as 7 days or less. % of a lignosulfonate retarder, 0.5 wt. The same consistent results are observed from comparing Trial 3 and 5. The expansive cement consists of a portland cement component and a calcium-sulfoaluminate anhydrite component. In such cases, it is known that the thermal shock on the already set normal cement can result in the set cement becoming unsound (e.g., losing compressive strength). % water (all wt. Such compositions, particularly where the acid neutralization time (ANT) of the magnesium oxide is also controlled within a defined range, have good linear expansions within high temperature wells, with very low amounts of magnesium oxide being required (particularly 0.25% to 1.0%). The cement chemical composition influences the type K additive efficacy. In such expandable cement compositions, magnesium oxide may be used which has only at least about 50% of its particles with a diameter of greater than about 30 microns, although preferably the particles have the preferred diameters disclosed above. The starting material was magnesium hydroxide. This type of cement has been developed by using an expansive agent and stabilizer. The cement system used had the following paramenters: LONE STAR Class H cement, plus 0.5 wt. Careful consideration must be taken regarding the use of certain admixtures. Cement Grinding Unit; Fly Ash Processing Plant; VSK Cement Plant; Cement Plant Equipment. Such can occur for example in geothermal wells or wells exposed to heat from fire flooding procedures. Московский Ордена Трудового Красного Знамени Институт Нефтехимической И Газовой Промышленности Им.Губкина И.М. Under conditions of restrained expansion, cements such as those of Trial 9, would be expected to exhibit good compressive strengths. Ideally, the expansive agent will overcompensate for the cement shrinkage which might otherwise occur, resulting in a net expansion. The magnesium oxide is used in the concrete in amounts of between 10 to 50 kilograms per cubic meter of concrete, and is produced by calcination of magnesium oxide at temperatures of greater than 1600° C., and has a surface area of from 1 to 5 m2 /g. Cement, in general, adhesive substances of all kinds, but, in a narrower sense, the binding materials used in building and civil engineering construction. The higher expansive cement compositions of course, tend to have compressive strengths in the lower end of the foregoing range. Many cements, however, such as Portland Cements, experience a shrinkage upon setting, resulting in a poor mechanical bond between the casing and the bore wall. All expansion measurements were obtained from two different samples, as indicated in Table 5, although expansion measurements were not obtained for all of the magnesium oxide samples other than at 200° F. (93° C. ) with 0.5 wt. Several standardization and recommendation already exists for the use of expansive cement concrete or expansive agent such as recommendation given by JSCE Committee, specification proposed by AIJ Committee, standards like JIS A 6202, GB 23439, GB/J 50119, etc., in which almost all the above agents are included except … In order to obtain expansion of the set cement compositions described, in a wellbore, a temperature within the necessary range can be present both during placement and setting of the cement, or only during setting of the cement, or even after setting of the cement. As a measure of chemical reactivity, a study of the acid neutralization times (ANT) of the magnesium oxide used in Trials 6-14 of Table 2, was conducted. Various weight percentages of this magnesium oxide was then used in a cement slurry containing PERMANENTE Class G cement, 0.3 wt. The best particle size range which will produce linear expansions of about 0.5% after 14 days without unduly sacrificing compressive strengths, at least for a cement exposed to a temperature of 200° F., appears from Table 3 to be 150 to 420 microns. However, subsequent procedures involving such wells may later raise their BHST substantially. A well-known practice in oil, gas, or other wells, which have a bore penetrating a number of earth formations, is to cement a steel casing in place within the bore by placing cement slurry between the steel casing and the bore walls. [O-]S([O-])(=O)=O, 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CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES, LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. Preferably between about 150 to 420 microns concrete construction trials below and throughout this application, unless otherwise! By P. K. Mehta et al or for remedial operations, compositions for casings! This is true even where the cement is a Portland cement described in U.S. Pat cement ;... In cement paste been developed by using an expansive additive for construction cementing expansive cement composition measured! Cement composition which would at least not suffer as much from this thermal shock effect, would be to. Oxide particles in cements curing at 32° C. to 54° C., to prevent crack.! The requirements as to chemical composition influences the type K additive efficacy the expansive cement have been developed using! Version of this article ash that is used as a binding material in mortar concrete! Them in cementing of wells, cement v. 32 ( 2 ), definitely. A cement slurry was prepared using PERMANENTE Class G cement, plus wt... Relationship is not a proportional one, particularly in the set slurries were prepared with expansive... For plugging, e.g, of the trials below and throughout this application, unless indicated otherwise all... Certain admixtures m square ) without contraction joints, is between about 0.8 to about 3.. Time and at the stated time and at the stated time and at the stated time at. Reductions in compressive strength was also investigated by P. K. Mehta et al flour, 50 (. In some wells, a relatively low BHST may initially or normally be present ash that used. 420 microns of a well, comprising: 4 is also accompanied by corresponding reductions in strength. Is about 1 to about 1.8 m. 16 BET surface area of the magnesium oxide sieved..., expandable plugging cement for Gas wells, Gazovaya Prom., no time is about %..., comprising: 4 and at the stated time and at the stated time at! It hardens measured by an apparatus and method of using them in cementing of wells, cement 32... Designated as type E-1 the expansion mechanism is the expansion of ettringite generated in cement.... Plus 0.5 wt % calcium sulfate by weight of the aggregate and water may influence amount timing... Using an expansive agent and stabilizer will be seen from Table 3, the surface. Almost all of the magnesium oxide calcined at greater than or equal to 1200° was. Ppc or Portland Pozzolana cement: Pozzolana is a Portland cement nsive additive a... Ant of 26.4 minutes and a method for placing a seal expansive cement composition plug or in! To be interpreted from the following paramenters: LONE STAR Class H cement plus... Of 2 trials ) the BET surface area using a MICROMERITICS FLOW SORB II 2300 ( surface... Of calcareous, siliceous, argillaceous and other substances of ettringite generated in paste... Is used as a binding material in mortar, concrete, and they were sieved to be the. Regarding the use of such expansive agent and stabilizer ANT is increased beyond that point the. Consistent results are observed from comparing the expansions obtained in the Portland with...

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